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GreenSep Nitro is a specifically designed SFC material for the separation of geometrical isomers and diastereomers. It is the column of choice in separating compounds that contain double bonds, aromatic groups, polarizable electrons and conjugated systems and exhibits a strong charge transfer system. GreenSep Nitro is unsurpassed for its separation capabilities and is available in analytical columns, preparative columns and bulk media.
GreenSep Basic exhibits a highly basic character and is ideally suited to high performance/high speed SFC preparative chromatography applications of chemicals containing amine groups. The chromatogram shown below contains chemicals that are functionalized with amine and acidic groups and is a prime example of the superior peak shape performance and separation capacity obtainable with the GreenSep Basic column. It also compares GreenSep Basic with GreenSep Ethyl Pyridine showing the superior reten- tion on GreenSep Basic when compared to GreenSep Ethyl Pyridine.
GreenSep Amino Phenyl is a specialty SFC stationary phase that has proven superior to conventional stationary phases in the areas of separation selectivity and loading capacity which was designed for the separation of amines, alcohols and acids by SFC without the use of additives. Works well in Normal Phase mixed mode offering pi-pi interaction and exhibits good base deactivation.
GreenSep FluoroBasic is based on fluorinated imidazole chemistry providing a highly basic and fluorinated character for this stationary phase. The addition of a fluorine groups into this stationary phase can be useful in promoting fluorophilic retention mechanism which can provide improved retention for fluorinated compounds. A fluorophilic retention mechanism can be particular useful in medicinal chemistry and drug discovery, where more than a third of newly approved small molecule drugs contain fluorine.
GreenSep Naphthyl is based on the rigid structure of pi electron rich and the naphthalene molecule provides a basis for many diastereomeric separations. A naphthalene based SFC material, with high bonding density and intrinsic base deactivation due to a rigid structure that also enables the shape selectivity needed for many diastereomeric separations. It also exhibits strong π-π interaction and charge transfer interactions and performs well for diastereomers separations and non-polar compounds. The unique properties of GreenSep Naphthyl place its selectivity between graphitized carbon and alkyl type stationary phases.
Unlike many SFC columns which require the addition of amine modifiers to the mobile phase to improve peak shape for basic compounds, GreenSep DEAP does not, greatly simplifying mobile phase composition and fraction collection. This makes GreenSep DEAP the SFC column of choice for the retention and rapid separation of chemical compounds containing strong amine groups.
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